| ID | 33037 |
| フルテキストURL | |
| 著者 |
Sabarudin, Akhmad
Department of Chemistry, Faculty of Science, Okayama University
大島 光子
Department of Chemistry, Faculty of Science, Okayama University
Ishii, Naoe
Laboratory Water Division, Nihon Millipore Ltd
本水 昌二
Department of Chemistry, Faculty of Science, Okayama University
|
| 抄録 | A highly sensitive fluorescence quenching method for the determination of silicate based on the formation of an ion associate between molybdosilicate and Rhodamine B (RB) in nitric acid medium was developed. A flow injection system coupled with a fluorescence detector was used for the measurement of fluorescence intensity at 560 and 580 nm as excitation and emission wavelengths, respectively. The calibration graph for Si showed a linear range of 0.1-5 ng cm(-3) with correlation coefficient of 0.9999, and the detection limit of 0.06 ng cm(-3). The proposed method was successfully applied to the determination of silicate in ultrapurified water with satisfactory results. |
| キーワード | ultrapurified water
ion associate
molybdosilicate
rhodamine B
flow injection
fluorescence quenching
|
| 備考 | Published with permission from the copyright holder.
This is published in Talanta, 2003 Vol.60 Issue.6 pp.1277-1285 Publisher URL: http://dx.doi.org/10.1016/S0039-9140(03)00234-0 Direct access to Thomson Web of Science record (C)2003 by Elsevier B.V. |
| 発行日 | 2003-08-29
|
| 出版物タイトル |
Talanta
|
| 巻 | 60巻
|
| 号 | 6号
|
| 開始ページ | 1277
|
| 終了ページ | 1285
|
| 資料タイプ |
学術雑誌論文
|
| 言語 |
英語
|
| 査読 |
有り
|
| DOI | |
| Web of Science KeyUT | |
| Submission Path | analytical_chemistry/29
|
