検索結果 886 件
| JaLCDOI | 10.18926/15685 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_10_2_25.pdf |
| 著者 | Torii, Sigeru| Tanaka, Hideo| |
| 抄録 | Ethyl dl-jasmonate (1a) and ethyl dl-2-epi-jasmonate (1b), novel constitutents in jasmin absolute from Italian Jasminum grandiflorum L, were prepared from 8-endo-(2'-cis-pentenyl)-3-oxo-2-oxa-bicyclo [3.2.1] octane, jasmine acid δ-lactone(2). Improvement of the preparation of the intermediate (9), a key precursor of (2), was made by different route via lactonization of (7) and/or (8). NMR and IR spectra (la) and (1b) are given. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1976-01-27 |
| 巻 | 10巻 |
| 号 | 2号 |
| 開始ページ | 25 |
| 終了ページ | 30 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307609 |
| JaLCDOI | 10.18926/15673 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_4_57.pdf |
| 著者 | Takahashi Teruo| Kitamura Yoshiro| |
| 抄録 | Although the stability of Newtonian liquid jet has been investigated experimentally and theoretically, many problems has remained unsolved. Especially, the stability of liquid jets in immiscible liquid systems has been little studied. Furthermore, one has to point out that the stability of jets may be influenced by the turbulence in the nozzle and the velocity profile. This work presents the experimental result about the effect of the nozzle length on the breakup length of liquid jets in the air and in the immiscible liquid, as the beginning of a systematic investigation of the influence by these factors on the breakup of jet. The dependence of the initial amplitude of surface disturbances on the nozzle geometry is presented for evaluating the effect of the nozzle length on the breakup length of laminar liquid jet in the air and in the immiscible liquid. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1969-09-01 |
| 巻 | 4巻 |
| 号 | 1号 |
| 開始ページ | 57 |
| 終了ページ | 64 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307482 |
| JaLCDOI | 10.18926/15672 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_4_51.pdf |
| 著者 | Takahashi Teruo| Akagi Yasuharu| |
| 抄録 | In this report, the average holding time of gas in foaming layer and the number of transfer units based on gas-phase of the Rotational-current tray were considered experimentally. The average holding time was determined by water-air system. On the other hand, the number of transfer units was determined by water-ammonia-air system that gas-phase resistance controlled. The average holding time increases with gas and liquid velocities, and does not change with the tray dimensions clearly. From the experimental results of the number of transfer units, it was found that the tray can be operated at high efficiency up to larger gas and liquid flow rates than that of sieve trays. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1969-09-01 |
| 巻 | 4巻 |
| 号 | 1号 |
| 開始ページ | 51 |
| 終了ページ | 56 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307449 |
| JaLCDOI | 10.18926/15667 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_9_2_53.pdf |
| 著者 | Torii, Sigeru| Tanaka, Hideo| Mandai, Tadakatsu| |
| 抄録 | This paper deals with graphical mass spectral data of the twentyfive compounds related to the preparation of methyl dl-jasmonate and its related materials. The fragmentations from the substituted cyclopentanones and norbornane derivatives can serve basic data for both characterization and elucidation of the structures of complex compounds referring to the preparation of principal components of jasmine flower. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1974-12-25 |
| 巻 | 9巻 |
| 号 | 2号 |
| 開始ページ | 53 |
| 終了ページ | 61 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307121 |
| JaLCDOI | 10.18926/15666 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_9_2_47.pdf |
| 著者 | Torii Sigeru| Uneyama Kenji| Ishihara Masakazu| |
| 抄録 | This paper describes mass spectral data from synthetic intermediates of linaloyl oxide. The fragmentation of sulfur functional groups including compounds l-8 would provide fruitful evidences for structural assignment of acyclic and alicyclic monoterpenoid precursors. Since, 1,3-dithianyl group in l,2, and 3 can provide a base peak and the elimination of the sulfinyl group from 7 and 8 is considered to occur at the initial stage of the fragmentation. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1974-12-25 |
| 巻 | 9巻 |
| 号 | 2号 |
| 開始ページ | 47 |
| 終了ページ | 51 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307176 |
| JaLCDOI | 10.18926/15641 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_6_57.pdf |
| 著者 | Monobe Kazuo| Murakami Yushi| Yokoyama Fumiyoshi| |
| 抄録 | Crystalline adducts of urea with n-alkanes (C(8)~C(20)) and n-l-alkanols (C(12)~C(18)) were prepared. From thermal analysis and X-ray diffraction study on the adducts, we found that the composition of adducts and the heat of decomposition can be obtained easily from the thermogram of adducts. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1971-09-01 |
| 巻 | 6巻 |
| 号 | 1号 |
| 開始ページ | 57 |
| 終了ページ | 60 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307947 |
| JaLCDOI | 10.18926/15640 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_6_53.pdf |
| 著者 | Yamashita Yuhiko| Monobe Kazuo| |
| 抄録 | Lamellar crystals of amylose V complexes with the 6(1), 7(1) and 8(1) helical configurations can be prepared from aqueous solutions of amylose by using various complexing agents. It is noted that the crystal shape can be explained by the symmetry of the unit cell in the basal plane and the chain packing in the unit cell is cOncerned with the symmetry of helical chains. The existence of 6(1), 7(1) and 8(1) heliccs which occurs stepwisc with the number of glucopyranose an intger is discussed. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1971-09-01 |
| 巻 | 6巻 |
| 号 | 1号 |
| 開始ページ | 53 |
| 終了ページ | 56 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307483 |
| JaLCDOI | 10.18926/15639 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_6_47.pdf |
| 著者 | Takahashi Katsuaki| Goto Yasumasa| |
| 抄録 | The glass forming limit by substitution of CdS for CdO in a CdO-B(2)0(3) glass was determined by chemical analysis. When x CdS-(60-x)CdO-40B(2)0(3) nominal mixtures in weight ratio were heated at 1100°C in flowing nitrogen gas for 1/2 hour, about 40~50% of mixed CdS and 10-15% of the mixed CdS were evaporated. The limit of nominal composition for glass forming was 10CdS-50CdO-40B(2)0(3) and the corresponding virtual composition after the above heat treatment was found to be 4.9CdS-46.4CdO-48.7B(2)O(3). Further addition of CdS made the melt devitrefied with CdS precipitation. D.C. conductivity measurements revealed that the current density was not linear with respect to the applied voltage, but the resistivity ranged around 10(12)Ω･cm for 4.1CdS-48.8CdO-47.1B(2)O(3) (virtual composition) glass and around 10(11.5)Ω·cm for 4.9CdS-46.4CdO-48.7B(2)O(3) glass. These sulphur containing glasses did not show photoconduction, although CdS-precipitated materials showed slight photoconductivity when disposed in ultra violet radiation. Apparent dielectric constant and tan 8 were also measured as a function of frequency, revealing a moderate dispersion in the CdS-precipitated glasses. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1971-09-01 |
| 巻 | 6巻 |
| 号 | 1号 |
| 開始ページ | 47 |
| 終了ページ | 52 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307147 |
| JaLCDOI | 10.18926/15625 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_3_77.pdf |
| 著者 | Monobe Kazuo| Yamashita Yuhiko| Fujiwara Yasuo| Fujiwara Yoshitaka| |
| 抄録 | We tried to clarify the crystallization mechanism of long chain polymers in solution under shearing stress using polyethylene. From the bright and dark field electron microscope observations and the electron diffraction study, we demonstrated that the resulting fibrous crystals consist of the central threads with an extended chain character and the lamellae with a folded chain character nucleated on the threads. The measurements of thermal and mechanical properties gave the additional confirmation for this suggestion. From these results we discussed the crystallization mechanism on the fibrous crystals. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1968-09-01 |
| 巻 | 3巻 |
| 号 | 1号 |
| 開始ページ | 77 |
| 終了ページ | 83 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307234 |
| JaLCDOI | 10.18926/15618 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_3_123.pdf |
| 著者 | Moriwake Tosio| Honjo Yozo| |
| 抄録 | Condensation of chroman-4-one with ethyl formate in the presence of sodium methoxide gave 3-hydroxymethylenechroman-4-one (II). Reaction of II with hydroxylamine hydrochloride, followed isomerization by potassium t-butoxide gave IV. 3-Cyano-3-methylchroman-4-one was obtained by methylation of IV or treatment of III with potassium t-butoxide and methyl iodide. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1968-09-01 |
| 巻 | 3巻 |
| 号 | 1号 |
| 開始ページ | 123 |
| 終了ページ | 126 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307167 |
| JaLCDOI | 10.18926/15617 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_3_119.pdf |
| 著者 | Takeda Akira| Wada Satosi| Uno Takaaki| Masuike Taketosi| Torii Sigeru| |
| 抄録 | The preparation of the title compounds as a new type of stable S-ylides has been described. The reaction of 1-dimethylsulfuranylidene-1-phenylsulfonyl-2-propanone (IIb) with lithium aluminium hydride was found to result in the formation of trans-phenylpropenylsulfone (IV), phenylsulfonyl-2-propanone (Ib), and an unidentified paraffin as major products. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1968-09-01 |
| 巻 | 3巻 |
| 号 | 1号 |
| 開始ページ | 119 |
| 終了ページ | 122 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307991 |
| JaLCDOI | 10.18926/15616 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_3_113.pdf |
| 著者 | Takeda Akira| Wada Satosi| |
| 抄録 | A series of α-monoalkylamino-α-arylacetamides and α-dialkylamino-α-arylacetamides have teen synthesized via the corresponding nitriles. Some of these compounds have been found to exhibit moderate activity as herbicides. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1968-09-01 |
| 巻 | 3巻 |
| 号 | 1号 |
| 開始ページ | 113 |
| 終了ページ | 117 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307743 |
| JaLCDOI | 10.18926/15615 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_3_107.pdf |
| 著者 | Takeda Akira| Torii Sigeru| Oka Hirotosi| |
| 抄録 | The electrochemical oxidation of trans-cinnamic acid in a mixed aqueous solution of acetic acid and methanol containing potassium hydroxide was studied. The separation of ketones and aldehydes from the neutral materials using Girard reagent P gave benzaldehyde, tolualdehydes, acetophenone, methylacetophenones, propiophenone, phenacyl acetate, and phenacyl alcohol. The mechanism of the anodic reaction of trans-cinnamic acid has been discussed. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1968-09-01 |
| 巻 | 3巻 |
| 号 | 1号 |
| 開始ページ | 107 |
| 終了ページ | 112 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307863 |
| JaLCDOI | 10.18926/15614 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_3_101.pdf |
| 著者 | Hirai Taketsugu| Takahashi Katsuaki| |
| 抄録 | Potential sweep voltammetries of Na(2)O·SiO(2) and Na(2)O·2SiO(2) at 730-1200°C were performed with the stationary platinum wire electrode and with the sweep rates of 40 and 120mV/sec. Although current-potential relation of Na(2)O . SiO(2) at 1200°C gave stationary S-shape pattern, those of the rest were transient modes with hysteresis. From the voltammetric considerations, a reversible oxygen electrode process where diffuion of free oxygen anion or silicate anion may be a rate-determining stage was tentatively proposed. Approximate estimations of decomposition voltage supported that a sole reaction process such as the decomposition of Na(2)O or indirect decomposition of SiO(2) in the melt was most probable. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1968-09-01 |
| 巻 | 3巻 |
| 号 | 1号 |
| 開始ページ | 101 |
| 終了ページ | 105 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307459 |
| JaLCDOI | 10.18926/15613 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_3_95.pdf |
| 著者 | Suefusa Kiyoshi| Monobe Kazuo| |
| 抄録 | Polyethylene was crytallized from the molten film under temperature gradient. As a result, the optically positive spherulites were observed, though only the negative spherulites had been observed previOusly in polyethylene. When the radial structure units twisted regulary in a spherulite are formed parallel to the surface of the film, the spberulite is usually optically negative in polyethylene. In this study, the temperature gradient normal to the surface of the film gives so significant tilt of the radial structure units formed to the surface of the film that the radial refractive index becomes larger than the tangential one under the transmitted polarized light and the spherulites have optically positive behavior. The optical behaviors of the polyethylene spherulites and the crystallizing condition were studied and discussed. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1968-09-01 |
| 巻 | 3巻 |
| 号 | 1号 |
| 開始ページ | 95 |
| 終了ページ | 100 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307360 |
| JaLCDOI | 10.18926/15612 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_3_89.pdf |
| 著者 | Monobe Kazuo| Yamashita Yuhiko| Fujiwara Yasuo| Fujiwara Masahiko| |
| 抄録 | It was shown that the fibrous crystals of isotactic polybutene-l crystallized from solution under shearing stress are also composed of the central threads with an extended chain character and the epitaxally deposited lamellae with a folded chain character. The characteristic behaviors in this polymer exist in; (1) that the resulting crystals possess the hexagonal modification of form 1'; (2) that at low polymer concentrations the lamellar crystals with an orthorhombic modification of form Ⅲ are precipitated in similar fashion to the case in the absence of stirring; (3) that the morphology in surface replica of thick deposited film is very similar to that of melt extruded polyethylene film crystallized in a highly stressed state. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1968-09-01 |
| 巻 | 3巻 |
| 号 | 1号 |
| 開始ページ | 89 |
| 終了ページ | 94 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307171 |
| JaLCDOI | 10.18926/15611 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_3_85.pdf |
| 著者 | Monobe Kazuo| Fujiwara Yasuo| Yamashita Yuhiko| Hironaka Kiyoshi| |
| 抄録 | Isotactic polypropylene was crystallized in the form of fibrous crystals from solution under shearing stress. The fibrous crystals consist of the oriented cluster of micro fibrils. From the electron microscopy and the electron diffraction study, it was found that the fine texture of this fibrous crystals is also the two component systems which are composed of the central threads with an extended chain character and the lamellae with a folded chain character deposited on the threads, as in polyethylene. Relatively larger lamellar structure than that of polyethylene was observed. The effect of crystallization conditions to the formation of the fibrous crystals from solution of isotactic polypropylene was described briefly. A characteristic melting behavior due to the melting of the central threads with an extended chain character was observed from the thermogram of differential scanning calorimeter. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1968-09-01 |
| 巻 | 3巻 |
| 号 | 1号 |
| 開始ページ | 85 |
| 終了ページ | 88 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307605 |
| JaLCDOI | 10.18926/15610 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_3_73.pdf |
| 著者 | Torii Sigeru| Isikawa Tatsuo| Takeda Akira| |
| 抄録 | Amide derivatives of γ-substituted paraconic and aconic acids have been synthesized. Ultraviolet spectra of the aconic acid derivatives showed characteristic fine structure in the region of 245 to 280 mμ. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1968-09-01 |
| 巻 | 3巻 |
| 号 | 1号 |
| 開始ページ | 73 |
| 終了ページ | 76 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307690 |
| JaLCDOI | 10.18926/15609 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_3_69.pdf |
| 著者 | Torii Sigeru| Funakosi Hitosi| Takeda Akira| |
| 抄録 | Monoamides of 5-substituted 4-methyl-3-carboxy-3(or 4)-alkenoic acids have been synthesized, starting with substituted itaconic anhydrides. The anhydride ring was opened by amines to afford N-aryl(or alkyl)-4-alkyl(or aryl)-3carboxy- 3(or 4}-alkenamides. The structure of the amide was elucidated by the comparison with the reference compound prepared from the corresponding Stobbe half-esters. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1968-09-01 |
| 巻 | 3巻 |
| 号 | 1号 |
| 開始ページ | 69 |
| 終了ページ | 72 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307752 |
| JaLCDOI | 10.18926/15607 |
|---|---|
| フルテキストURL | Mem_Sch_Eng_OU_3_63.pdf |
| 著者 | Takahashi Katsuaki| Kambara Ginjiro| Okahara Masamichi| |
| 抄録 | Spectrophotometric investigations were carried out on soda-lime-silica glasses containing iron in high content, corresponding to 4.9 wt.% Fe(2)O(3), and melted under the various reducing conditions, as a part of series of studies on the redox behavior of glass. Absorption measurement was made in the range from 340 mμ to 1000 mμ. Ferric ions could not be reduced to ferrous ions completely even by the amount of carbon of four equivalents. The ratio of the strength of light absorption at 1000 mμ as a typical band of Fe(2+) ions and that at 380mμ of Fe(3+) ions was expressed as E(1000)/E(380), which was examined for glass compositions as well as various carbon amount added to glass batches. The ratio decreases as the carbon amount increases and increases with decreasing content of Na(2)O or CaO. These changes of spectrophotometric properties of glasses were discussed from the view point of state of the the iron ions. Besides, some results on oxidized glasses were also added. |
| 出版物タイトル | Memoirs of the School of Engineering, Okayama University |
| 発行日 | 1968-09-01 |
| 巻 | 3巻 |
| 号 | 1号 |
| 開始ページ | 63 |
| 終了ページ | 68 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307848 |