| ID | 58546 |
| フルテキストURL | |
| 著者 |
Murai, Masahito
Graduate School of Natural Science and Technology, Okayama University
ORCID
Kaken ID
publons
researchmap
Takai, Kazuhiko
Graduate School of Natural Science and Technology, Okayama University
ORCID
Kaken ID
publons
researchmap
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| 抄録 | A rhenium complex catalyzed the formation of 2-iodo-1H-indene derivatives through iodine and hydrogen migration of 3-iodopropargyl ethers. The reaction proceeded via generation of 1-iodoalkenylrhenium carbene species by sequential 1,2-iodine and 1,5-hydrogen shifts with readily available precursors under neutral conditions. The reaction mechanism and the reactivity of the generated alkenylcarbene species were also investigated.
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| キーワード | anti-markovnikov addition
silyl enol ethers
terminal alkynes
metal vinylidenes
cycloisomerization
ruthenium
complexes
derivatives
carbene
functionalization
|
| 発行日 | 2019-08-08
|
| 出版物タイトル |
Organic Letters
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| 巻 | 21巻
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| 号 | 17号
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| 出版者 | American Chemical Society
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| 開始ページ | 6756
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| 終了ページ | 6760
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| ISSN | 15237060
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| NCID | AA11347843
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| 資料タイプ |
学術雑誌論文
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| 言語 |
英語
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| OAI-PMH Set |
岡山大学
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| 論文のバージョン | author
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| PubMed ID | |
| DOI | |
| Web of Science KeyUT | |
| 関連URL | isVersionOf https://doi.org/10.1021/acs.orglett.9b02380
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| 助成機関名 |
文部科学省
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| 助成番号 | 18H03911
19H02719
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