| ID | 70784 |
| フルテキストURL | |
| 著者 |
Mitsudo, Koichi
Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
ORCID
Kaken ID
publons
researchmap
Magata, Ryo
Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Sato, Eisuke
Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Nakamura, Tomoya
Institute for Chemical Research, Kyoto University
Wakamiya, Atsushi
Institute for Chemical Research, Kyoto University
Suga, Seiji
Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
ORCID
Kaken ID
researchmap
|
| 抄録 | Boranils, difluoroboron complexes with imine and phenoxy moieties, were synthesized by iodide-promoted demethylative borylation. The use of appropriate amounts of BF3•OEt2, Bu4NI, and Et3N enabled the highly efficient synthesis of boranils. Boranils containing heteroaromatics and highly π-extended boranils were also readily obtained by this method. Their physical properties were studied, and the properties were consistent with those calculated by DFT calculations.
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| キーワード | boranil
boron
demethylative borylation
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| 発行日 | 2026-05-29
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| 出版物タイトル |
Bulletin of the Chemical Society of Japan
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| 巻 | 99巻
|
| 号 | 6号
|
| 出版者 | Oxford University Press (OUP)
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| 開始ページ | uoag070
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| ISSN | 0009-2673
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| NCID | AA00580132
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| 資料タイプ |
学術雑誌論文
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| 言語 |
英語
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| OAI-PMH Set |
岡山大学
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| 著作権者 | © The Author(s) 2026.
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| 論文のバージョン | publisher
|
| DOI | |
| 関連URL | isVersionOf https://doi.org/10.1093/bulcsj/uoag070
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| ライセンス | https://creativecommons.org/licenses/by/4.0/
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| Citation | Koichi Mitsudo, Ryo Magata, Eisuke Sato, Tomoya Nakamura, Atsushi Wakamiya, Seiji Suga, Synthesis of boranils by iodide-mediated demethylative borylation and their properties, Bulletin of the Chemical Society of Japan, Volume 99, Issue 6, June 2026, uoag070, https://doi.org/10.1093/bulcsj/uoag070
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