| ID | 71301 |
| フルテキストURL | |
| 著者 |
Hanaya, Tadashi
Department of Chemistry, Faculty of Science, Okayama University
Kaken ID
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Yamamoto, Hiroshi
Department of Chemistry, Faculty of Science, Okayama University
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| 抄録 | Additivity constants for phosphorus were estimated for the prediction of vicinal 1H–1H coupling constants by means of an additivity rule in a series of pyranose analogs having phosphorus as the ring heteroatom. The experimental J values were well reproduced by employing the proposed additivity constants with a small overall root-mean-square difference of 0.32 Hz. The prediction of coupling constants was employed for the investigation of conformational equilibria of pyranose analogs having a phosphinyl group in the ring or on the ring-carbon.
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| キーワード | Phosphosugar
Pyranose analogs having a C–P bond
Vicinal coupling constants
Additivity rule for substituents
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| 備考 | © 1998 Elsevier Science Ltd. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/
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| 発行日 | 1998-01
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| 出版物タイトル |
Carbohydrate Research
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| 巻 | 306巻
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| 号 | 1-2号
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| 出版者 | Elsevier BV
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| 開始ページ | 157
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| 終了ページ | 162
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| ISSN | 0008-6215
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| NCID | AA00598932
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| 資料タイプ |
学術雑誌論文
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| 言語 |
英語
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| 著作権者 | © 1998 Elsevier Science Ltd.
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| 論文のバージョン | author
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| DOI | |
| Web of Science KeyUT | |
| 関連URL | isVersionOf https://doi.org/10.1016/s0008-6215(97)10038-6
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| ライセンス | https://creativecommons.org/licenses/by-nc-nd/4.0/
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