| ID | 71206 |
| フルテキストURL | |
| 著者 |
Shimanouchi, Toshinori
Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
ORCID
Kaken ID
researchmap
Deguchi, Koji
Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Yasuhara, Kazuma
Division of Materials Science, Nara Institute of Science and Technology (NAIST)
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| 抄録 | A conversion of 5-hydroxymethylfurfural to 2,5-frandicarboxylic acid (FDCA) was catalyzed by using a catalyst of PtBi-activated carbon (PtBi/C) combined with vesicles made of phospholipid. No alteration of the electron state of the PtBi/C by vesicles was observed. However, FDCA was obtained under mild-temperature and base-free conditions. The yield of FDCA depended on the hydration nature of vesicles. It was therefore suggested that vesicles gave bound water as a novel driving force for the reaction. The present finding would explore an application of vesicles to new catalytic reactions that are different from conventional biochemical reactions.
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| キーワード | 2,5-frandicarboxylic acid
metal-supported catalyst
vesicles
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| 発行日 | 2025-05-24
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| 出版物タイトル |
Chemistry Letters
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| 巻 | 54巻
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| 号 | 6号
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| 出版者 | Oxford University Press (OUP)
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| 開始ページ | upaf104
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| ISSN | 0366-7022
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| NCID | AA00603318
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| 資料タイプ |
学術雑誌論文
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| 言語 |
英語
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| OAI-PMH Set |
岡山大学
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| 著作権者 | © The Author(s) 2025.
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| 論文のバージョン | publisher
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| DOI | |
| Web of Science KeyUT | |
| 関連URL | isVersionOf https://doi.org/10.1093/chemle/upaf104
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| ライセンス | https://creativecommons.org/licenses/by-nc/4.0/
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| Citation | Toshinori Shimanouchi, Koji Deguchi, Kazuma Yasuhara, Yukitaka Kimura, Vesicle-combined PtBi/C catalyst for base-free conversion of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid, Chemistry Letters, Volume 54, Issue 6, June 2025, upaf104, https://doi.org/10.1093/chemle/upaf104
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| 助成情報 |
( 国立研究開発法人科学技術振興機構 / Japan Science and Technology Agency )
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