| JaLCDOI | 10.18926/15352 |
|---|---|
| フルテキストURL | Mem_Fac_Eng_OU_35_35.pdf |
| 著者 | 島村 薫| 内田 哲也| 井上 智博| |
| 抄録 | Rigid polymer, poly(p-phenylene benzobisthiazole), formed lamellar crystals where the molecular chains were oriented perpendicular to the lamellae. It was supposed that, because of wide distribution in the chain length, the lamellar surface bristled with the chain cilia among which many voids were included. Crystallographically, this region afforded us a transitional structure from full to deficient packings of chains. The structure was analyzed using the scanning probe microscope. In the course the method for imaging one molecular chain end was developed. From the images it was concluded that an isolated long cilius did not move so violently at room temperature. |
| 出版物タイトル | Memoirs of the Faculty of Engineering, Okayama University |
| 発行日 | 2001-03-27 |
| 巻 | 35巻 |
| 号 | 1-2号 |
| 開始ページ | 35 |
| 終了ページ | 40 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307784 |
| JaLCDOI | 10.18926/15350 |
|---|---|
| フルテキストURL | Mem_Fac_Eng_OU_35_29.pdf |
| 著者 | 島村 薫| Munesawa Yuhji| 内田 哲也| |
| 抄録 | Poly (ethylene-block-vinyl alcohol), which consisted of both hydrophobic and hydrophilic blocks, was prepared by using polyethylene single crystals as starting material. Polyethylene single crystals reacted with fuming nitric acid resulting in long methylene chains with functional groups such as COOH and NO(2) at the ends (the chain length were almost same as the lamellar thickness of polyethylene single crystal). The functionalized methylene chains were allowed to react with 4-aminostyrene to give corresponding amides, i.e., methylene chains with vinyl groups at the ends (macromer). The macromers were extended by block-copolymerization with vinyl acetate, then saponified resulting in PE/PVA block co-polymer. The block copolymer was molded into sheets which were subsequently heat-treated in contact with hydrophilic or hydrophobic media. Depending on the media, the sheet surface changed at high temperature reversibly from hydrophilic to hydrophobic and vice versa. The surface property was fixed by quenching because both blocks were able to crystallize. Thus the surface of this material can be tailored for various purposes at high temperature, and then used in stable at room temperature. |
| 出版物タイトル | Memoirs of the Faculty of Engineering, Okayama University |
| 発行日 | 2001-03-27 |
| 巻 | 35巻 |
| 号 | 1-2号 |
| 開始ページ | 29 |
| 終了ページ | 34 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002307155 |
| JaLCDOI | 10.18926/14136 |
|---|---|
| フルテキストURL | Mem_Fac_Eng_39_1_16.pdf |
| 著者 | 内田 哲也| 石丸 早苗| 島村 薫| 宇治 章人| 松尾 俊彦| 大月 洋| |
| 抄録 | PE film was treated with fuming nitric acid at 80℃ for 20 min, resulting in introduction of COOH moieties on the film surface. The COOH’s were reacted with ethylenediamine, whose amino groups were used for linking with (2-[4-(dibutylamino)phenyl]ethenyl)-3-carboxy-methylbenzo-thiazolium, photoelectric dye (NK-5962), which absorbs visible light and converts the photon energy to electric potentials. The dye molecules were immobilized on the PE film surface and they were able to stimulate chick retinal tissues on incidence of visible light. These facts hopefully lead to development of an artificial retinal prosthesis. |
| 出版物タイトル | Memoirs of the Faculty of Engineering, Okayama University |
| 発行日 | 2005-01 |
| 巻 | 39巻 |
| 号 | 1号 |
| 開始ページ | 16 |
| 終了ページ | 20 |
| ISSN | 0475-0071 |
| 言語 | 英語 |
| 論文のバージョン | publisher |
| NAID | 120002308066 |
| 著者 | 内田 哲也| |
|---|---|
| 発行日 | 2002-09-30 |
| 出版物タイトル | |
| 資料タイプ | 学位論文 |