start-ver=1.4
cd-journal=joma
no-vol=21
cd-vols=
no-issue=17
article-no=
start-page=6756
end-page=6760
dt-received=
dt-revised=
dt-accepted=
dt-pub-year=2019
dt-pub=20190808
dt-online=
en-article=
kn-article=
en-subject=
kn-subject=
en-title=
kn-title=Rhenium-Catalyzed Cyclization via 1,2-Iodine and 1,5-Hydrogen Migration for the Synthesis of 2-Iodo-1H-indenes
en-subtitle=
kn-subtitle=
en-abstract=
kn-abstract=A rhenium complex catalyzed the formation of 2-iodo-1H-indene derivatives through iodine and hydrogen migration of 3-iodopropargyl ethers. The reaction proceeded via generation of 1-iodoalkenylrhenium carbene species by sequential 1,2-iodine and 1,5-hydrogen shifts with readily available precursors under neutral conditions. The reaction mechanism and the reactivity of the generated alkenylcarbene species were also investigated.
en-copyright=
kn-copyright=

en-aut-name=MuraiMasahito
en-aut-sei=Murai
en-aut-mei=Masahito
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=1
ORCID=

en-aut-name=TakaiKazuhiko
en-aut-sei=Takai
en-aut-mei=Kazuhiko
kn-aut-name=
kn-aut-sei=
kn-aut-mei=
aut-affil-num=2
ORCID=

affil-num=1
en-affil=Graduate School of Natural Science and Technology, Okayama University
kn-affil=

affil-num=2
en-affil=Graduate School of Natural Science and Technology, Okayama University
kn-affil=
en-keyword=anti-markovnikov addition
kn-keyword=anti-markovnikov addition
en-keyword=silyl enol ethers
kn-keyword=silyl enol ethers
en-keyword=terminal alkynes
kn-keyword=terminal alkynes
en-keyword=metal vinylidenes
kn-keyword=metal vinylidenes
en-keyword=cycloisomerization
kn-keyword=cycloisomerization
en-keyword=ruthenium
kn-keyword=ruthenium
en-keyword=complexes
kn-keyword=complexes
en-keyword=derivatives
kn-keyword=derivatives
en-keyword=carbene
kn-keyword=carbene
en-keyword=functionalization
kn-keyword=functionalization
END