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ID 61962
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Fu, Liyan Graduate School of Natural Science and Technology, Okayama University
You, Jingwen Graduate School of Natural Science and Technology, Okayama University
Nishihara, Yasushi Research Institute for Interdisciplinary Science, Okayama University ORCID Kaken ID publons researchmap
Abstract
This paper describes the synthesis of unsymmetrical biaryls by the palladium-catalyzed cross-coupling reaction of acyl chlorides with potassium perfluorobenzoates. This transformation is unique in that it involves simultaneous decarbonylation and decarboxylation under redox-neutral conditions. Compared to conventional cross-coupling protocols for the synthesis of unsymmetrical biaryls, the two reactants in this synthetic strategy can be readily prepared from abundant and inexpensive aromatic carboxylic acids.
Note
Communication
This is an Accepted Manuscript of an article published by Royal Society of Chemistry.
Published Date
2021-04-18
Publication Title
Chemical Communications
Volume
volume57
Issue
issue30
Publisher
Royal Society of Chemistry (RSC)
Start Page
3696
End Page
3699
ISSN
1359-7345
Content Type
Journal Article
language
English
OAI-PMH Set
岡山大学
Copyright Holders
© The Royal Society of Chemistry 2021
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isVersionOf https://doi.org/10.1039/d1cc00202c