| ID | 11478 |
| JaLCDOI | |
| Sort Key | 21
|
| FullText URL | |
| Author |
Nakatsu Shogo
Tsuboi, Sadao
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| Abstract | Diels-Alder reactions of 5,5,5-trichloro-3-penten-2-one and ethyl 4,4,4-trichloro-2-butenoate with cyclopentadiene in the presence of a chiral Lewis acid gave exo-2-acetyl-endo-3-trichloromethyl-bicyclo[2.2.1]hept-5-ene and exo-2-ethoxycarbonyl-endo-3-trichloromethylbicyclo[2.2.1]hept-5-ene with 40% and 7% e.e., respectively.
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| Keywords | asymmetric reaction
Diels-Alder reaction
asymmetric Diels-Alder reaction
chiral Lewis acid
trichloromethy group
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| Publication Title |
岡山大学環境理工学部研究報告
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| Published Date | 2004-02-27
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| Volume | volume9
|
| Issue | issue1
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| Publisher | 岡山大学環境理工学部
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| Publisher Alternative | Faculty of Environmental Science and Technology, Okayama University
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| Start Page | 163
|
| End Page | 166
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| ISSN | 1341-9099
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| NCID | AN10529213
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| Content Type |
Departmental Bulletin Paper
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| OAI-PMH Set |
岡山大学
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| language |
English
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| File Version | publisher
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| NAID | |
| Eprints Journal Name | fest
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