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JaLCDOI 10.18926/fest/19742
FullText URL 004_147_158.pdf
Author Chen, Danping| Watanabe, Tomohiro| Miura, Yoshinari| Nanba, Tokuro|
Abstract Photo-induced phenomena such as photoconductive and photovoltaic effects were investigated for the glasses in CdO-Bi(2)O(3)-Al(2)O(3) system. Photoconductive effect was characterized by a slow decay of photocurrent (persitent photoconductivity). The decay rate decreased with increasing CdO content and decreasing Bi(2)O(3) content. Photovoltage was very small at room temperature but increased to an obvious value on heating. The photoconductivity and photovoltage were increased with CdO content and enhanced by heat treatment in air. The valence band spectra of X-ray photoelectron spectroscopy showed that the hybridization of Cd 4d and O 2p orbitals increases with decreasing Bi(2)O(3) content and increasing CdO content in the glasses. As the results maximum tends to flat. This type of band structure inhibits the rapid recombination of electrons and holes. The persistent photoconductivity of the glasses may be attributed to deep energy level of DX centers. Deep energy levels of the glasses are able to prevent the recombination because they have a repulsive barrier for both electron emission and capture.
Keywords Photoconductivity Photovoltage Persistent photoconductivity CdO-Bi(2)O(3)-Al(2)O(3) glasses Electronic state
Publication Title 岡山大学環境理工学部研究報告
Published Date 1999-02-26
Volume volume4
Issue issue1
Start Page 147
End Page 158
ISSN 1341-9099
language English
File Version publisher
NAID 120002309190
JaLCDOI 10.18926/19622
FullText URL Mem_Fac_Eng_OU_31_1_5.pdf
Author Shimamura, Kaoru| Zhang Chunxiao| Uchida, Tetsuya|
Abstract Rigid polymer poly(p-phenylene benzobisthiazole) was crystallized from dilute solution. Electron microscopy showed that upon quenching, flat fibrils with several nm thick were produced. Subsequent heat treatment in solvent changed the fibril into "shish-kebab". On the other hand, by isothermal crystallization, an aggregate of parallel rod-like crystals was obtained. The molecular chains were accommodated normal to the rod. Based on the observation of crystal morphology, the isothermal crystallization mechanism was proposed. Because of regidity of polymer chains and wide distribution of the molecular length, the chain ends were inevitably included within the crystals resulting in crystal defects such as axial shift, lattice curvature and edge dislocation which were directly observed by lattice imaging.
Publication Title Memoirs of the Faculty of Engineering, Okayama University
Published Date 1996-12-27
Volume volume31
Issue issue1
Start Page 5
End Page 10
ISSN 0475-0071
language English
File Version publisher
NAID 120002309167
Author Date, Yoshinori|
Published Date 1958-07-31
Publication Title 岡山医学会雑誌
Volume volume70
Issue issue7
Content Type Journal Article
Author Nakarai, Akihide|
Published Date 1972-12-30
Publication Title 岡山医学会雑誌
Volume volume84
Issue issue11-12
Content Type Journal Article
Author Tanaka, Hideo|
Published Date 1971-02-28
Publication Title 岡山医学会雑誌
Volume volume83
Issue issue1-2
Content Type Journal Article
Author Suga, Ken|
Published Date 1973-04-30
Publication Title 岡山医学会雑誌
Volume volume85
Issue issue3-4
Content Type Journal Article
Author Amano, Tetsuki|
Published Date 1978-06-30
Publication Title 岡山医学会雑誌
Volume volume90
Issue issue5-6
Content Type Journal Article
Author Ohashi, Takeo|
Published Date 1977-08-30
Publication Title 岡山医学会雑誌
Volume volume89
Issue issue7-8
Content Type Journal Article
Author Yamada, Osamu|
Published Date 1978-02-28
Publication Title 岡山医学会雑誌
Volume volume90
Issue issue1-2
Content Type Journal Article
Author Fujii, Toshitake|
Published Date 1977-08-30
Publication Title 岡山医学会雑誌
Volume volume89
Issue issue7-8
Content Type Journal Article
Author Ohmori, Sachio|
Published Date 1980-10-30
Publication Title 岡山医学会雑誌
Volume volume92
Issue issue9-10
Content Type Journal Article
Author Miyake, Ikuo|
Published Date 1980-04-30
Publication Title 岡山医学会雑誌
Volume volume92
Issue issue3-4
Content Type Journal Article
Author Ikeda, Komei|
Published Date 1979-10-30
Publication Title 岡山医学会雑誌
Volume volume91
Issue issue9-10
Content Type Journal Article
Author Ikeda, Komei|
Published Date 1979-10-30
Publication Title 岡山医学会雑誌
Volume volume91
Issue issue9-10
Content Type Journal Article
Author Kuramitsu, Makoto|
Published Date 1980-02-28
Publication Title 岡山医学会雑誌
Volume volume92
Issue issue1-2
Content Type Journal Article
Author Harada, Yasuhiro|
Published Date 1979-04-30
Publication Title 岡山医学会雑誌
Volume volume91
Issue issue3-4
Content Type Journal Article
Author Ohmori, Sachio|
Published Date 1981-02-28
Publication Title 岡山医学会雑誌
Volume volume93
Issue issue1-2
Content Type Journal Article
Author Kanatani, Tomohisa|
Published Date 1984-08-30
Publication Title 岡山医学会雑誌
Volume volume96
Issue issue7-8
Content Type Journal Article
Author Tokuda, Masaaki|
Published Date 1983-04-30
Publication Title 岡山医学会雑誌
Volume volume95
Issue issue3-4
Content Type Journal Article
Author Motoki, Mototsugu|
Published Date 1984-02-28
Publication Title 岡山医学会雑誌
Volume volume96
Issue issue1-2
Content Type Journal Article