| ID | 61271 |
| FullText URL | |
| Author |
Chen, Qiang
Graduate School of Natural Science and Technology, Okayama University
Fu, Liyan
Graduate School of Natural Science and Technology, Okayama University
You, Jingwen
Graduate School of Natural Science and Technology, Okayama University
Nishihara, Yasushi
Research Institute for Interdisciplinary Science, Okayama University
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| Abstract | Nickel-catalyzed decarbonylative alkynylation of acyl fluorides with terminal silylethynes under copper-free conditions is described. This newly developed method has a wide substrate scope, affording internal silylethynes in moderate to high yields. The formation of 1,3-diynes as homocoupled products and conjugate enones as carbonyl-retentive products were effectively suppressed.
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| Keywords | nickel catalysis
decarbonylation
silylalkynes
alkynylation
acyl fluorides
sila-Sonogashira–Hagihara reaction
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| Note | This is an Accepted Manuscript of an article published by Thieme Gruppe.
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| Published Date | 2020-10-28
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| Publication Title |
Synlett
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| Publisher | Thieme Gruppe
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| ISSN | 0936-5214
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| NCID | AA10731110
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| Content Type |
Journal Article
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| language |
English
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| OAI-PMH Set |
岡山大学
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| Copyright Holders | © 2020. Thieme.
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| File Version | author
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| DOI | |
| Web of Science KeyUT | |
| Related Url | isVersionOf https://doi.org/10.1055/s-0040-1705954
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