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ID 57347
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Author
Wang, Lei Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University ORCID publons
Fujii, Mayu Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University
Namba, Misa Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University
Yamaji, Minoru Division of Molecular Science, Graduate School of Science and Engineering, Gunma University
Okamoto, Hideki Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID researchmap
Abstract
2,3-Naphthalimide derivatives incorporating trifluoroacetamido (3a) and methansulfonamido (3b) functionalities at the 1-position were prepared and their intramolecular excited state proton transfer (ESIPT) fluorescence and responses to metal ions were investigated. Compound 3a displayed normal fluorescence in the amide form in toluene and MeCN and no response to metal cations in the corresponding amidate ion form. In contrast, compound 3b gave off dual emission assignable to normal and ESIPT fluorescence. Additionally, the amidate form of compound 3b displayed off-on fluorescence response to Ca2+.
Keywords
Fluorescence
ESIPT
Naphthalimide
Ca2+ probe
Note
© 2019 Elsevier Ltd. This manuscript version is made available under the CC-BY-NC-ND 4.0 License.http://creativecommons.org/licenses/by-nc-nd/4.0/.This is the accepted manuscript version. The formal published version is available at [https://doi.org/10.1016/j.tetlet.2019.151189].
Published Date
2019-09-20
Publication Title
Tetrahedron Letters
Volume
volume60
Issue
issue43
Publisher
PERGAMON-ELSEVIER SCIENCE
Start Page
151189
ISSN
00404039
NCID
AA00861801
Content Type
Journal Article
language
English
OAI-PMH Set
岡山大学
Copyright Holders
© 2019 Elsevier Ltd.
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isVersionOf https://doi.org/10.1016/j.tetlet.2019.151189
License
https://creativecommons.org/licenses/by-nc-nd/4.0/
Citation
Lei Wang, Mayu Fujii, Misa Namba, Minoru Yamaji, Hideki Okamoto, Fluorescence properties of amido-substituted 2,3-naphthalimides: Excited-state intramolecular proton transfer (ESIPT) fluorescence and responses to Ca2+ ions, Tetrahedron Letters, Volume 60, Issue 43, 2019, 151189, ISSN 0040-4039, https://doi.org/10.1016/j.tetlet.2019.151189.
Open Access (Publisher)
non-OA
Open Archive (publisher)
Non-OpenArchive