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JaLCDOI 10.18926/fest/11578
Title Alternative Consideration for the correlation between basicity of oxide glasses and chemical shift of O1s binding energy in XPS
FullText URL 003_145_156.pdf
Author Nanba, Tokuro| Miura, Yoshinari|
Abstract Binding energy of O1s core electron measured in XPS is a candidate to determine new scale of Lewis basicity of oxide ion in glass. Some mathematical expressions for the basicity or XPS chemical shift, such as charge parameter and optical basicity, are compared with experimental O1s binding energy in binary alkali oxide glasses. The expressions so far in use need some modification in parameters. A new empirical expression introduced in this paper gives new concept and universal scale of basicity.
Publication Title 岡山大学環境理工学部研究報告
Published Date 1998-01-14
Volume volume3
Issue issue1
Start Page 145
End Page 156
ISSN 1341-9099
language Japanese
File Version publisher
NAID 120002313359
JaLCDOI 10.18926/fest/11541
Title Alternative Upconversion property and light scattering in Tm(3+)-doped glass-ceramics
FullText URL 007_119_125.pdf
Author Miura, Yoshinari| Ding, Yong| Murata, Takashi| Himei, Yusuke| Nanba, Tokuro|
Abstract Glass-ceramics containing Pb(x)Cd(1-x)F(2) microcrystallites were prepared through heat treatment of Tm(3+)/Yb(3+)doped SiO(2)-Al(2)O(3)-PbF(2) glasses. The crystallite size was controlled by varying the heat-treatment time. By changing glass composition, two types of strong optical scattering, Rayleigh and Mie scattering modes were observed for the glass ceramics. In the case of Rayleigh scattering, the scattering region expanded to the long-wavelength side with increasing the heat-treatment time. On the other hand, in the case of Mie scattering, the region were hardly dependent on wavelength, and visible light was widely scattered. It was argued that the different scattering phenomena were caused by the different size of the crystallites or their morphogical texture. Furthermore, the glass-ceramics with strong optical scattering showed higher upconversion fluorescence intensity than the matrix glass. The mechanisms for the enhanced upconversion due to the scattering were discussed.
Keywords Optical scattering Glass-ceramics Oxyfluoride glass Microcrystallite Upconversion fluorescence
Publication Title 岡山大学環境理工学部研究報告
Published Date 2002-03-22
Volume volume7
Issue issue1
Start Page 119
End Page 125
ISSN 1341-9099
language Japanese
File Version publisher
NAID 120002313480
JaLCDOI 10.18926/fest/11538
Title Alternative Effects of ultrasonic treatment on the preparation of transparent glass-ceramic phosphor
FullText URL 007_113_118.pdf
Author Inoue, Teruhide| Nakashima, Mizuho| Nanba, Tokuro| Miura, Yoshinari|
Abstract The effects of ultrasonic surface treatment (UST) on the crystallization behavior and optical emission properties were investigated for the transparent glass-ceramics prepared from calcium aluminosilicate glasses co-doped with Eu(2+), Nd(3+). The glass-ceramics A were prepared by sintering a glass 45CaO・45Al(2)O(3)・10SiO(2) (mol%) containing 0.5Eu(2)O(3)+1Nd(2)O(3) under a 2% H(2)+98% Ar reducing atmosphere. In the glass-ceramics A, three crystalline phases, CaAl(2)O(4) (CA), CaAl(4)O(7) (CA2) and Ca(2)Al(2)SiO(7) (CAS) were commonly confirmed by X-ray diffraction. No drastic change in the amount of the precipitated crystalline phases was observed even in the case using UST of CA powders. It was suggested that the optical emission properties of the glass-ceramics A was responsible for the CA2 crystals. The glass-ceramics B were also prepared from a 51CaO・42Al(2)O(3)・7SiO(2) glass. The CA crystals were separately precipitated in the glass-ceramics B. In particular, a large amount of CA was successfully produced by stirring the UST suspension to prevent the sedimentation of the UST particles. The glass-ceramic B so-prepared showed strong photoluminescence but weak phosphorescence compared with other glass-ceramics B, indicating that the photoluminescence and phosphorescence were originated in different electron-trapping levels. The amount of the trap levels associated with the long lasting phosphorescence, such as oxygen vacancies, was probably small in the glass-ceramic B prepared with the stirring UST.
Keywords ultrasonic surface treatment (UST) surface crystallization glass-ceramics long lasting phosphorescence calcium aluminosilicate glass
Publication Title 岡山大学環境理工学部研究報告
Published Date 2002-03-22
Volume volume7
Issue issue1
Start Page 113
End Page 118
ISSN 1341-9099
language Japanese
File Version publisher
NAID 120002313433
JaLCDOI 10.18926/fest/11528
Title Alternative Damage factors analysis for small embankment dams due to the Hyogoken-Nambu earthquake special to Hokudan Town
FullText URL 007_055_074.pdf
Author Fujii, Hiroaki| Kunimasa, Kana| Nanba, Akiyo| Yokomizo, Takayuki| Nishimura, Shin-ichi| Shimada, Kiyoshi| Hori, Toshio| Nishiyama, Tatsuro| Wakitani, Yoshiaki|
Abstract This study was performed to clarify which factors affected damage to take-ike (small embankment dams for irrigation in Japanese) of Hokudan Town on Awaji Island in western Japan due to Hyogoken-Nambu earthquake. Multivariate and ordinary statistical analysis were carried out using documentary data (181 damaged and 328 undamaged dams), and ordinary one was done for the results investigated in situ. The model for the multivariate analysis was created with 13 items and 94 categories for 4 groups (Location, Geology Structure, and History of Dam). As a result, the factors causing to damage for dam are (1) the nearest fault (Nojima, Mizukoshi and D2), (2) embankment volume (the larger the more), (3) angle of crest axis to epicenter (diagonal and normal), (4) distance to the nearest fault (less than 500 m), (5) distance to the epicenter (8 to 14 km which almost agree to the location of seismic intensity 7 JMA), (6) play view of dam axis (3 or 4 axes), (7) angle of crest axis to nearest fault (diagonal and normal), (8) elevation of dam site (over 100 m), (9) surface geology of dam site (non-cohesive soil), (10) era of construction (prior to 1891), and (11) soil properties of embankment (constructed of sand, smaller penetration resistance).
Keywords Earth dam earthquake damage site investigation statistical analysis case study
Publication Title 岡山大学環境理工学部研究報告
Published Date 2002-03-22
Volume volume7
Issue issue1
Start Page 55
End Page 74
ISSN 1341-9099
language Japanese
File Version publisher
NAID 120002314039
JaLCDOI 10.18926/fest/11476
Title Alternative Evaluation of Surface State of Ceramic Particles Suspended in Aqueous Solution by Potentiometric Titration Method
FullText URL 009_153_162.pdf
Author Miura, Yoshinari| Nanba, Tokuro| Shinoda, Masakatsu|
Abstract Surface states of ceramic particles such as SiO(2), Al(2)O(3), Si(3)N(4) and so on suspended in aqueous alkaline solutions were successfully and easily determined by a potentiometric titration method. Isoelctric point, iep and excess surface charge density were classified and evaluated for many ceramic particles from the view points of aggregation and dispersion of particles and solubility in aqueous solution.
Keywords potentiometric titration method isoelctric point excess surface charge density ceramic particle suspension aqueous solution
Publication Title 岡山大学環境理工学部研究報告
Published Date 2004-02-27
Volume volume9
Issue issue1
Start Page 153
End Page 162
ISSN 1341-9099
language Japanese
File Version publisher
NAID 120002313753
JaLCDOI 10.18926/fest/11475
Title Alternative Material Recycling of Municipal Waste Slags by Using Phase Separation of Glass
FullText URL 012_161_165.pdf
Author Imaoka, Takuya| Sakida, Shinichi| Nanba, Tokuro| Miura, Yoshinari|
Abstract A novel recycling process of municipal waste slags obtaining Fe-free colorless materials was developed by using a phase separation of borosilicate glass. B(2)O(3) was added to a simulated waste slag to promote the phase separation. The slag glasses were heat-treated above glass transition temperatures, from which phase separation was successfully induced. The phase-separated slag glasses were still colored in black due to Fe ions, and after soaking in acid, they were successfully bleached, obtaining colorless solids. According to compositional analyses, no Fe ions were confirmed in the remaining insolubles, indicating that Fe ions were preferentially incorporated into the borate-rich phases soluble in acid. The main constituent of the colorless solids was SiO(2) and the end products obtained in the present process were expected as an alternative of pure silica glass.
Keywords slag recycling colorless glass phase separation
Publication Title 岡山大学環境理工学部研究報告
Published Date 2007-03-15
Volume volume12
Issue issue1
Start Page 161
End Page 165
ISSN 1341-9099
language Japanese
File Version publisher
NAID 120002313957
Author Namba, Kazuhiko|
Published Date 1996-02-01
Publication Title 岡山大学農学部学術報告
Volume volume85
Issue issue1
Content Type Departmental Bulletin Paper
Author Ikeda, Yasumasa| Nanba, Syoji| Masuda, Masaharu|
Published Date 1995-02-01
Publication Title 岡山大学農学部学術報告
Volume volume84
Issue issue1
Content Type Departmental Bulletin Paper
Author Elbatawi, Ibrahim E. A.| Mohri, Kentaro| Namba, Kazuhiko|
Published Date 1998-02
Publication Title 岡山大学農学部学術報告
Volume volume87
Issue issue1
Content Type Departmental Bulletin Paper
Author Chen, Yong Bo| Mohri, Kentaro| Namba, Kazuhiko|
Published Date 1998-02
Publication Title 岡山大学農学部学術報告
Volume volume87
Issue issue1
Content Type Departmental Bulletin Paper
Author Liu, Houqing| Mohri, Kentaro| Namba, Kazuhiko|
Published Date 1998-02
Publication Title 岡山大学農学部学術報告
Volume volume87
Issue issue1
Content Type Departmental Bulletin Paper
Author Ta, Na| Mohri, Kentaro| Namba, Kazuhiko| Monta, Mitsuji|
Published Date 2003-02
Publication Title 岡山大学農学部学術報告
Volume volume92
Issue issue1
Content Type Departmental Bulletin Paper
Author Nanba, Koichi|
Published Date 2004-03-25
Publication Title
Content Type Thesis or Dissertation
Author Namba, Katsuyuki|
Published Date 2005-03-25
Publication Title
Content Type Thesis or Dissertation
Author 難波 治|
Published Date 1992-03-28
Publication Title
Content Type Thesis or Dissertation
Author 難波 明博|
Published Date 2003-03-25
Publication Title
Content Type Thesis or Dissertation
Author 難波 淳子|
Published Date 2001-03-25
Publication Title
Content Type Thesis or Dissertation
Author 難波 良文|
Published Date 1997-03-31
Publication Title
Content Type Thesis or Dissertation
Author 難波 良司|
Published Date 1962-03-31
Publication Title
Content Type Thesis or Dissertation
Author 難波 祐三郎|
Published Date 2000-03-25
Publication Title
Content Type Thesis or Dissertation