| ID | 57242 |
| FullText URL | |
| Author |
Kunishige, Takahiro
Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, Okayama University
Sawada, Daisuke
Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, Okayama University
Kaken ID
researchmap
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| Abstract | A new procedure for the iron-catalyzed synthesis of enamides from ketoximes was developed, and its mechanism was proposed. A unique reduction system, with the concerted use of KI and Na2S2O4, was involved. The reaction exhibited a wide substrate scope and gave good yields in a short reaction time. The procedure is operationally simple and also applicable for the large-scale synthesis.
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| Keywords | Ketoxime
Enamide synthesis
Iron catalyst
One-electron reduction
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| Note | This fulltext will be available in May 2021
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| Published Date | 2019-06-13
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| Publication Title |
Tetrahedron Letters
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| Volume | volume60
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| Issue | issue24
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| Publisher | PERGAMON-ELSEVIER SCIENCE
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| Start Page | 1562
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| End Page | 1565
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| ISSN | 00404039
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| Content Type |
Journal Article
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| language |
English
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| OAI-PMH Set |
岡山大学
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| File Version | author
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| DOI | |
| Web of Science KeyUT | |
| Related Url | isVersionOf https://doi.org/10.1016/j.tetlet.2019.05.006
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| Citation | Takahiro Kunishige, Daisuke Sawada, Efficient and practical synthesis of N-acetyl enamides from ketoximes by unique iron catalytic system, Tetrahedron Letters, Volume 60, Issue 24, 2019, Pages 1562-1565, ISSN 0040-4039, https://doi.org/10.1016/j.tetlet.2019.05.006.
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| Funder Name |
Japan Society for the Promotion of Science
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| 助成番号 | 17H06173
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| Open Access (Publisher) |
non-OA
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| Open Archive (publisher) |
Non-OpenArchive
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