| ID | 58409 |
| FullText URL | |
| Author |
Murai, Masahito
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
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Uemura, Erika
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Takai, Kazuhiko
Division of Applied Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University
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| Abstract | Amines have been identified to greatly accelerate the intermolecular anti-Markovnikov addition of carbon nucleophiles to unactivated terminal alkynes. Using a combination of [ReBr(CO)3(thf)]2 and iPr2NEt, construction of cyclic all-carbon quaternary centers was achieved with various 1,3-ketoesters, diketones, and diesters with lower catalyst loading under milder conditions. The type of addition could be easily controlled by choice of additive, highlighting the unique features of rhenium catalysis
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| Keywords | rhenium
anti-Markovnikov addition
1,3-dicarbonyl compound
vinylidene
amine
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| Published Date | 2018-05-04
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| Publication Title |
ACS Catalysis
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| Volume | volume8
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| Issue | issue6
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| Publisher | American Chemical Society
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| Start Page | 5454
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| End Page | 5459
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| ISSN | 2155-5435
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| NCID | AA12599706
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| Content Type |
Journal Article
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| language |
English
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| OAI-PMH Set |
岡山大学
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| DOI | |
| Web of Science KeyUT | |
| Related Url | isVersionOf http://dx.doi.org/10.1021/acscatal.8b01338
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| Funder Name |
Ministry of Education, Culture, Sports, Science and Technology
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| 助成番号 | 26248030
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