| ID | 58256 |
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| Author |
Araki, Yuya
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Miyoshi, Natsumi
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Morimoto, Kazuki
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
Kudoh, Takayuki
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
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Mizoguchi, Haruki
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
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Sakakura, Akira
Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University
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| Abstract | A formal total synthesis of manzacidin B is described. beta,beta-Disubstituted gamma-hydroxy-beta-aminoalcohol, the key structure of manzacidin B, is stereoselectively constructed via sequential Henry reactions. By taking advantage of noncovalent interactions, such as intramolecular hydrogen bonding and chelation, we could diastereodivergently control the stereoselectivity of the Henry reaction.
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| Note | This document is the Accepted Manuscript version of a Published Work that appeared in final form inJournal of Organic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.9b02811.
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| Published Date | 2019-12-18
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| Publication Title |
Journal of Organic Chemistry
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| Volume | volume85
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| Issue | issue2
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| Publisher | American Chemical Society
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| Start Page | 798
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| End Page | 805
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| ISSN | 0022-3263
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| NCID | AA00704100
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| Content Type |
Journal Article
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| language |
English
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| OAI-PMH Set |
岡山大学
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| File Version | author
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| PubMed ID | |
| DOI | |
| Web of Science KeyUT | |
| Related Url | isVersionOf https://doi.org/10.1021/acs.joc.9b02811
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| License | https://creativecommons.org/licenses/by-nc-nd/4.0/deed.ja
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| Citation | J. Org. Chem. 2020, 85, 2, 798-805 Publication Date:December 18, 2019 https://doi.org/10.1021/acs.joc.9b02811
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| Funder Name |
Japan Society for the Promotion of Science
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| 助成番号 | 18K0S123
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