| ID | 34180 |
| FullText URL | |
| Author |
Hayashi, N
Takehara, Z
Katagiri, A
|
| Abstract | The acid-base properties of the ZnBr[2]-NaBr melts at 623 K were investigated on the basis of the electromotive force measurements of a zinc-zinc concentration cell. The following two chemical equilibria were postulated to describe the acid-base character of the melts ZBnr[2]+Br[-]=ZnBr[3][-] K[1] ZnBr[3][-]+Br[-] =ZnBr[4][2+] K[2] The equilibrium constants K[1] and K[2], were determined to be 5.0×10, and 1.0×10[2], respectively, at 623 K |
| Keywords | liquid mixtures
aluminium compounds
sodium compounds
bromine compounds
chemical equilibrium
electrochemical analysis
thermodynamic properties
thermochemistry
electric potential
|
| Note | Digital Object Identifer:10.1149/1.2097508
Published with permission from the copyright holder. This is the institute's copy, as published in Journal of the Electrochemical Society, February 1989, Volume 136, Issue 9, Pages 2606-2608. Publisher URL:http://dx.doi.org/10.1149/1.2097508 Copyright © 1989 The Electrochemical Society, Inc. All rights reserved. |
| Published Date | 1988-11-30
|
| Publication Title |
Journal of the Electrochemical Society
|
| Volume | volume136
|
| Issue | issue9
|
| Start Page | 2606
|
| End Page | 2608
|
| Content Type |
Journal Article
|
| language |
English
|
| Refereed |
True
|
| DOI | |
| Submission Path | physical_and_theoretical_chemistry/22
|
