| ID | 70909 |
| FullText URL | |
| Author |
Nose, Keito
Department of Chemistry, Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
Yamaji, Minoru
Program of Applied Chemistry, Cluster of Materials and Environment, Gunma University
Mori, Tadashi
Research Center for Environmental Preservation and Graduate School of Engineering, The University of Osaka
Tani, Fumito
Institute for Materials Chemistry and Engineering, Kyushu University
Goto, Kenta
Institute for Materials Chemistry and Engineering, Kyushu University
Okamoto, Hideki
Department of Chemistry, Graduate School of Environmental, Life, Natural Science and Technology, Okayama University
ORCID
Kaken ID
researchmap
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| Abstract | The fluorescence properties and photostabilities of (E)-diarylethenes (DPEs), featuring two 3-phenanthryl moieties, were investigated. Pristine (E)-di-1,2-(3-phenanthryl)ethene and its ester derivative, respectively referred to as DPE-H and DPE-E, exhibited blue fluorescence. However, they underwent a two-step photoreaction sequence that yielded [7]helicenes, resulting in a gradual reduction of the fluorescence intensity. In contrast, the imide-fused derivative DPE-I displayed intense green fluorescence and it was unexpectedly photostable in solution, maintaining its highly efficient fluorescent nature even after prolonged light exposure. DPE-I, thus, provides a new type of highly efficient and robust diarylethene fluorophore.
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| Keywords | diarylethene
fluorescence
phenanthreneimide
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| Published Date | 2025-05
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| Publication Title |
Chemistry Letters
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| Volume | volume54
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| Issue | issue5
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| Publisher | Oxford University Press (OUP)
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| Start Page | upaf091
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| ISSN | 0366-7022
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| NCID | AA00603318
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| Content Type |
Journal Article
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| language |
English
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| OAI-PMH Set |
岡山大学
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| Copyright Holders | © The Author(s) 2025.
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| File Version | publisher
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| DOI | |
| Web of Science KeyUT | |
| Related Url | isVersionOf https://doi.org/10.1093/chemle/upaf091
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| License | https://creativecommons.org/licenses/by-nc/4.0/
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| Citation | Keito Nose, Minoru Yamaji, Tadashi Mori, Fumito Tani, Kenta Goto, Hideki Okamoto, Highly emissive and robust diarylethene fluorophore incorporating imide-fused phenanthryl moieties, Chemistry Letters, Volume 54, Issue 5, May 2025, upaf091, https://doi.org/10.1093/chemle/upaf091
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