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ID 57242
著者
Kunishige, Takahiro Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, Okayama University
Sawada, Daisuke Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, Okayama University Kaken ID researchmap
抄録
A new procedure for the iron-catalyzed synthesis of enamides from ketoximes was developed, and its mechanism was proposed. A unique reduction system, with the concerted use of KI and Na2S2O4, was involved. The reaction exhibited a wide substrate scope and gave good yields in a short reaction time. The procedure is operationally simple and also applicable for the large-scale synthesis.
キーワード
Ketoxime
Enamide synthesis
Iron catalyst
One-electron reduction
備考
This fulltext will be available in May 2021
発行日
2019-06-13
出版物タイトル
Tetrahedron Letters
60巻
24号
出版者
PERGAMON-ELSEVIER SCIENCE
開始ページ
1562
終了ページ
1565
ISSN
00404039
資料タイプ
学術雑誌論文
言語
English
OAI-PMH Set
岡山大学
論文のバージョン
author
DOI
Web of Science KeyUT
関連URL
isVersionOf https://doi.org/10.1016/j.tetlet.2019.05.006
Citation
Takahiro Kunishige, Daisuke Sawada, Efficient and practical synthesis of N-acetyl enamides from ketoximes by unique iron catalytic system, Tetrahedron Letters, Volume 60, Issue 24, 2019, Pages 1562-1565, ISSN 0040-4039, https://doi.org/10.1016/j.tetlet.2019.05.006.
助成機関名
日本学術振興会
助成番号
17H06173
オープンアクセス(出版社)
非OA
オープンアーカイブ(出版社)
非OpenArchive