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ID 11477
Eprint ID
11477
フルテキストURL
タイトル(別表記)
Efficient Chain Extension Reaction of Poly (butylene terephthalate) by using Crystallization
著者
井原 誠司 岡山大学
城間 弥 岡山大学
山崎 慎一 岡山大学
木村 邦生 岡山大学
抄録
Plastics are quite important materials for not only industrial usages but also our daily life. Many plastics are difficult to reuse because they are susceptible to UV, hydrolysis and so on leading to the reduction of molecular weight. Among them, poly (butylenes terephthalate) (PBT) is a valuable materials prepared by polycondensation reaction, and PBT has the same limitation to reuse. Hence, efficient chain extension reaction for recovered PBT has been needed to improve the properties damaged by chain scission. In this study, new chain extension reaction had been examined by using crystallization as pre-treatment. Isothermal crystallization at 161℃ concentrated the chain end-groups on the surface of the crystals, and chain extension reaction at 210℃, which was lower than the melting temperature of PBT, enhanced the molecular weight significantly compared with the reaction over the melting temperature. It concluded that the pre-treatment of crystallization was favorable for the efficient chain extension reaction and this result provided the new technology for the effective reuse of the plastics.
キーワード
Polyester
material recycle
crystallization
chain extension reaction
発行日
2007-03-15
出版物タイトル
岡山大学環境理工学部研究報告
出版物タイトル(別表記)
Journal of the Faculty of Environmental Science and Technology, Okayama University
12巻
1号
出版者
岡山大学環境理工学部
出版者(別表記)
Faculty of Environmental Science and Technology, Okayama University
開始ページ
167
終了ページ
171
ISSN
1341-9099
NCID
AN10529213
資料タイプ
紀要論文
関連URL
http://www.okayama-u.ac.jp/user/est/homeJapan.html
言語
Japanese
論文のバージョン
publisher
査読
無し
Eprints Journal Name
fest