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ID 57490
フルテキストURL
著者
Iwasaki, Masayuki Research Institute for Interdisciplinary Science, Okayama University ORCID Kaken ID
Xu, Jie Graduate School of Natural Science and Technology, Okayama University
Tani, Yukari Graduate School of Natural Science and Technology, Okayama University
Fu, Liyan Graduate School of Natural Science and Technology, Okayama University
Ikemoto, Yuichi Graduate School of Natural Science and Technology, Okayama University
Ura, Yasuyuki Department of Chemistry, Biology, and Environmental Science, Faculty of Science, Nara Women’s University
Nishihara, Yasushi Research Institute for Interdisciplinary Science, Okayama University ORCID Kaken ID researchmap
抄録
A copper-catalyzed chloroamination of alkenes with chlorotrimethylsilane and N-fluorobenzenesulfonimide has been developed. The reactions were complete within 1 h at 120 degrees C by means of microwave heating. The present chloroamination proceeds with a perfect regioselectivity and is compatible with various functional groups. The preliminary mechanistic investigation revealed that the reaction involves a radical process. The utility of the present method was demonstrated by scalable, operationally simple and safe system.
キーワード
Chloroamination
Copper catalyst
Alkenes
発行日
2019-01-10
出版物タイトル
Chemistry Letters
48巻
3号
出版者
Chemical Society of Japan
開始ページ
281
終了ページ
283
ISSN
03667022
NCID
AA00603318
資料タイプ
学術雑誌論文
言語
English
OAI-PMH Set
岡山大学
論文のバージョン
author
DOI
Web of Science KeyUT
関連URL
isVersionOf https://doi.org/10.1246/cl.180937
助成機関名
日本学術振興会
助成番号
16K17901