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ID 57914
著者
Iwasaki, Masayuki Research Institute for Interdisciplinary Science, Okayama University ORCID Kaken ID
Nonaka, Kosei Graduate School of Natural Science and Technology, Okayama University
Zou, Song
Sawanaka, Yuta Graduate School of Natural Science and Technology, Okayama University
Shinozaki, Takaaki Graduate School of Natural Science and Technology, Okayama University
Fujii, Tomoya Graduate School of Natural Science and Technology, Okayama University
Nakajima, Kiyohiko Graduate School of Natural Science and Technology, Okayama University
Nishihara, Yasushi Research Institute for Interdisciplinary Science, Okayama University ORCID Kaken ID researchmap
抄録
Copper-catalyzed regioselective aminothiolation of terminal and internal alkenes with N-fluorobenzenesulfonimide and thiols has been developed. The three-component reaction is promoted by the addition of dimethyl sulfide. In addition to aromatic alkenes, aliphatic alkenes are subjected to the reaction, affording various aminothiolation adducts as single regioisomers. The radical process is proposed by preliminary mechanistic studies, involving radical trap and radical clock experiments.
備考
This fulltext will be available in Nov 2020
発行日
2019-11-04
出版物タイトル
Journal of Organic Chemistry
84巻
23号
出版者
American Chemical Society
開始ページ
15373
終了ページ
15379
ISSN
0022-3263
NCID
AA00704100
資料タイプ
学術雑誌論文
言語
English
OAI-PMH Set
岡山大学
論文のバージョン
author
PubMed ID
DOI
Web of Science KeyUT
関連URL
isVersionOf https://doi.org/10.1021/acs.joc.9b02392
Citation
J. Org. Chem. 2019, 84, 23, 15373-15379 Publication Date:November 7, 2019 https://doi.org/10.1021/acs.joc.9b02392
助成機関名
日本学術振興会
助成番号
16K17901