REPO

Memoirs of the Faculty of Engineering, Okayama University 3巻 1号
1968-09-01 発行

New Stable Sulfonium Ylides. 1-Dimethylsulfuranylidene-l-phenylsulfonyl-2-propanone and Related Compounds

Takeda Akira Department oj Synthetics Chemistry
Wada Satosi Department oj Synthetics Chemistry
Uno Takaaki Department oj Synthetics Chemistry
Masuike Taketosi Department of Applied Chemistry, Fuculty of Engineering, Osaka City University
Torii Sigeru Department of Industrial Chemistry, School of Engineering, Okayama University
Publication Date
1968-09-01
Abstract
The preparation of the title compounds as a new type of stable S-ylides has been described. The reaction of 1-dimethylsulfuranylidene-1-phenylsulfonyl-2-propanone (IIb) with lithium aluminium hydride was found to result in the formation of trans-phenylpropenylsulfone (IV), phenylsulfonyl-2-propanone (Ib), and an unidentified paraffin as major products.
ISSN
0475-0071
NCID
AA00733903
NAID