Memoirs of the Faculty of Engineering, Okayama University
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Memoirs of the School of Engineering, Okayama University
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New Stable Sulfonium Ylides. 1-Dimethylsulfuranylidene-l-phenylsulfonyl-2-propanone and Related Compounds
Takeda Akira
Department oj Synthetics Chemistry
Wada Satosi
Department oj Synthetics Chemistry
Uno Takaaki
Department oj Synthetics Chemistry
Masuike Taketosi
Department of Applied Chemistry, Fuculty of Engineering, Osaka City University
Torii Sigeru
Department of Industrial Chemistry, School of Engineering, Okayama University
抄録
The preparation of the title compounds as a new type of stable S-ylides has been described. The reaction of 1-dimethylsulfuranylidene-1-phenylsulfonyl-2-propanone (IIb) with lithium aluminium hydride was found to result in the formation of trans-phenylpropenylsulfone (IV), phenylsulfonyl-2-propanone (Ib), and an unidentified paraffin as major products.
ISSN
0475-0071
NCID
AA00733903