Memoirs of the Faculty of Engineering, Okayama University 3巻 1号
1968-09-01 発行
Takeda Akira
Department oj Synthetics Chemistry
Wada Satosi
Department oj Synthetics Chemistry
Uno Takaaki
Department oj Synthetics Chemistry
Masuike Taketosi
Department of Applied Chemistry, Fuculty of Engineering, Osaka City University
Torii Sigeru
Department of Industrial Chemistry, School of Engineering, Okayama University
The preparation of the title compounds as a new type of stable S-ylides has been described. The reaction of 1-dimethylsulfuranylidene-1-phenylsulfonyl-2-propanone (IIb) with lithium aluminium hydride was found to result in the formation of trans-phenylpropenylsulfone (IV), phenylsulfonyl-2-propanone (Ib), and an unidentified paraffin as major products.