Memoirs of the Faculty of Engineering, Okayama University
Published by Faculty of Enginerring, Okayama University <Formerly known as>
Memoirs of the School of Engineering, Okayama University
<Availability>
Some items are not available because of decision by its author or publisher.
Permalink : http://ousar.lib.okayama-u.ac.jp/15544
Reaction of α-Chloro-N-arylisobutyrimidyl Chloride with Ethyl Malonate(1)
Takeda Akira
Department of Industrial Chemistry
Wada Satosi
Department of Industrial Chemistry
Ohmura Yutaka
Kurasiki Rayon Co., Ltd
抄録
a-Chloro-N-arylisobutyrimidyl chloride (I) reacted with ethyl sodiomalonate to afford N-aryl-2,2-dimethyl-3 carbethoxysuccinimide. This reaction seems to proceed in a different mechanism from that of the synthesis of tetronic acids(2) and is supposed to involve a primary attack of the carbanion at the a-carbon atom of the chloride followed by the cyclization.
ISSN
0475-0071
NCID
AA00733903