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ID 46985
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Author
Nakahara, Takahiro
Yu, Peng
Abstract
Treatment of aromatic aldimines with terminal alkenes in the presence of a rhenium catalyst, [HRe(CO)(4)](n), gives 2-alkenylbenzylamines in good to excellent yields. This reaction proceeds via the insertion of the alkene into a C-H bond at the ortho-position of the imino group of the aromatic aldimine followed by sequential beta-hydride elimination from the formed alkyl rhenium intermediate and then by hydrogenation of the imino group of the aldimine.
Keywords
Rhenium
Insertion
Hydrogen transfer
Aldimine
Alkene
Published Date
2011-01-01
Publication Title
Journal of Organometallic Chemistry
Volume
volume696
Issue
issue1
Publisher
Elsevier Science SA.
Start Page
348
End Page
351
ISSN
0022-328X
NCID
AA00704122
Content Type
Journal Article
language
英語
Copyright Holders
© 2011 Elsevier B.V. All rights reserved.
File Version
author
Refereed
True
DOI
Web of Sience KeyUT