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ID 58755
Author
Fu, Liyan Graduate School of Natural Science and Technology, Okayama University
Chen, Qiang Graduate School of Natural Science and Technology, Okayama University
Wang, Zhenhua Graduate School of Natural Science and Technology, Okayama University
Nishihara, Yasushi Research Institute for Interdisciplinary Science, Okayama University ORCID Kaken ID publons researchmap
Abstract
Palladium-catalyzed decarbonylative alkylation reactions of acyl fluorides have been developed using alkylboranes having β-hydrogens. A wide range of functional groups were well tolerated, even at the high temperature required for decarbonylation. This protocol provides a diverse C(sp2)–C(sp3) bond formation via a highly efficient decarbonylative process. The hemilabile bidentate ligand DPPE plays a crucial role for retardation of the undesired β-hydride elimination.
Note
This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Organic Letters, copyright © American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.0c00542.
This fulltext is available in May 2021.
Published Date
2020-05-05
Publication Title
Organic Letters
Volume
volume22
Issue
issue6
Publisher
American Chemical Society
Start Page
2350
End Page
2353
ISSN
15237060
NCID
AA11347843
Content Type
Journal Article
language
英語
File Version
author
PubMed ID
DOI
Web of Science KeyUT
Related Url
isVersionOf https://doi.org/10.1021/acs.orglett.0c00542