このエントリーをはてなブックマークに追加
ID 57490
FullText URL
Author
Iwasaki, Masayuki Research Institute for Interdisciplinary Science, Okayama University ORCID Kaken ID
Xu, Jie Graduate School of Natural Science and Technology, Okayama University
Tani, Yukari Graduate School of Natural Science and Technology, Okayama University
Fu, Liyan Graduate School of Natural Science and Technology, Okayama University
Ikemoto, Yuichi Graduate School of Natural Science and Technology, Okayama University
Ura, Yasuyuki Department of Chemistry, Biology, and Environmental Science, Faculty of Science, Nara Women’s University
Nishihara, Yasushi Research Institute for Interdisciplinary Science, Okayama University ORCID Kaken ID publons researchmap
Abstract
A copper-catalyzed chloroamination of alkenes with chlorotrimethylsilane and N-fluorobenzenesulfonimide has been developed. The reactions were complete within 1 h at 120 degrees C by means of microwave heating. The present chloroamination proceeds with a perfect regioselectivity and is compatible with various functional groups. The preliminary mechanistic investigation revealed that the reaction involves a radical process. The utility of the present method was demonstrated by scalable, operationally simple and safe system.
Keywords
Chloroamination
Copper catalyst
Alkenes
Published Date
2019-01-10
Publication Title
Chemistry Letters
Volume
volume48
Issue
issue3
Publisher
Chemical Society of Japan
Start Page
281
End Page
283
ISSN
03667022
NCID
AA00603318
Content Type
Journal Article
language
英語
OAI-PMH Set
岡山大学
File Version
author
DOI
Web of Science KeyUT
Related Url
isVersionOf https://doi.org/10.1246/cl.180937
Funder Name
Japan Society for the Promotion of Science
助成番号
16K17901