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ID 34180
FullText URL
Author
Hayashi, N
Takehara, Z
Katagiri, A
Abstract

The acid-base properties of the ZnBr[2]-NaBr melts at 623 K were investigated on the basis of the electromotive force measurements of a zinc-zinc concentration cell. The following two chemical equilibria were postulated to describe the acid-base character of the melts ZBnr[2]+Br[-]=ZnBr[3][-] K[1] ZnBr[3][-]+Br[-] =ZnBr[4][2+] K[2] The equilibrium constants K[1] and K[2], were determined to be 5.0×10, and 1.0×10[2], respectively, at 623 K

Keywords
liquid mixtures
aluminium compounds
sodium compounds
bromine compounds
chemical equilibrium
electrochemical analysis
thermodynamic properties
thermochemistry
electric potential
Note
Digital Object Identifer:10.1149/1.2097508
Published with permission from the copyright holder. This is the institute's copy, as published in Journal of the Electrochemical Society, February 1989, Volume 136, Issue 9, Pages 2606-2608.
Publisher URL:http://dx.doi.org/10.1149/1.2097508
Copyright © 1989 The Electrochemical Society, Inc. All rights reserved.
Published Date
1988-11-30
Publication Title
Journal of the Electrochemical Society
Volume
volume136
Issue
issue9
Start Page
2606
End Page
2608
Content Type
Journal Article
language
英語
Refereed
True
DOI
Submission Path
physical_and_theoretical_chemistry/22