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ID 56915
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Author
Zhou, Xiaoyu The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry, Institute for Planetary Materials, Okayama University ORCID
Tanaka, Ryoji The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry, Institute for Planetary Materials, Okayama University ORCID Kaken ID publons researchmap
Yamanaka, Masahiro The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry, Institute for Planetary Materials, Okayama University
Sakaguchi, Chie The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry, Institute for Planetary Materials, Okayama University
Nakamura, Eizo The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry, Institute for Planetary Materials, Okayama University Kaken ID publons researchmap
Abstract
Sample decomposition using inverse aqua regia at elevated temperatures and pressures (e.g., Carius tube or high‐pressure asher) is the most common method used to extract highly siderophile elements (HSEs: Ru, Rh, Pd, Re, Os, Ir, Pt and Au) from geological samples. Recently, it has been recognised that additional HF desilicification is necessary to better recover HSEs, potentially contained within silicate or oxide minerals in mafic samples, which cannot be dissolved solely by inverse aqua regia. However, the abundance of interfering elements tends to increase in the eluent when conventional ion‐exchange purification procedures are applied to desilicified samples. In this study, we developed an improved purification method to determine HSEs in desilicified samples. This method enables the reduction of the ratios of isobaric and polyatomic interferences, relative to the measured intensities of HSE isotope masses, to less than a few hundred parts per million. Furthermore, the total procedural blanks are either comparable to or lower than conventional methods. Thus, this method allows accurate and precise HSE measurements in mafic and ultramafic geological samples, without the need for interference corrections. Moreover, the problem of increased interfering elements, such as Zr for Pd and Cr for Ru, is circumvented for the desilicified samples.
Keywords
highly siderophile elements
desilicification
isotope dilution method
high resolution ICP-MS
N-TIMS
Published Date
2019-03-20
Publication Title
Geostandards and Geoanalytical Research
Volume
volume43
Issue
issue4
Publisher
John Wiley
Start Page
611
End Page
633
ISSN
16394488
NCID
AA11984494
Content Type
Journal Article
language
英語
OAI-PMH Set
岡山大学
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author
DOI
Web of Science KeyUT
Related Url
isVersionOf https://doi.org/10.1111/ggr.12280
License
https://creativecommons.org/licenses/by-nc-nd/4.0/deed.ja
Funder Name
Japan Society for the Promotion of Science
助成番号
16K05578