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ID 58546
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Author
Murai, Masahito Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
Takai, Kazuhiko Graduate School of Natural Science and Technology, Okayama University ORCID Kaken ID publons researchmap
Abstract
A rhenium complex catalyzed the formation of 2-iodo-1H-indene derivatives through iodine and hydrogen migration of 3-iodopropargyl ethers. The reaction proceeded via generation of 1-iodoalkenylrhenium carbene species by sequential 1,2-iodine and 1,5-hydrogen shifts with readily available precursors under neutral conditions. The reaction mechanism and the reactivity of the generated alkenylcarbene species were also investigated.
Keywords
anti-markovnikov addition
silyl enol ethers
terminal alkynes
metal vinylidenes
cycloisomerization
ruthenium
complexes
derivatives
carbene
functionalization
Published Date
2019-08-08
Publication Title
Organic Letters
Volume
volume21
Issue
issue17
Publisher
American Chemical Society
Start Page
6756
End Page
6760
ISSN
15237060
NCID
AA11347843
Content Type
Journal Article
language
英語
OAI-PMH Set
岡山大学
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author
PubMed ID
DOI
Web of Science KeyUT
Related Url
isVersionOf https://doi.org/10.1021/acs.orglett.9b02380
Funder Name
Ministry of Education, Culture, Sports, Science and Technology
助成番号
18H03911
19H02719