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ID 11617
Eprint ID
11617
FullText URL
Title Alternative
Synthesis of Polythiophen Cluster in Lattice Space of Hexagonal Faujasite
Author
Matsuda, Motohide
Yagi, Katsuhito
Uehara, Hirofumi
Sato, Mitsuo
Abstract
Encapsulation of thiophen and bithiophen in two kinds of hexagonal faujasites (Na-EMT and H-EMT) with various concentration of Cu(2+) ions have been investigated and characterized by means of themoanalytic and spectroscopic methods. From the results, it was found that the progress of polymerization of thiophen and bithiophen in the lattice space depended on Cu(2+) contents, and the encapsulation of thiophen in Na-EMT and H-EMT with Cu(2+) ions yielded polythiophen clusters with electron states of bipolaron. On the other hand, polythiophen clusters synthesized by the encapsulation of bithiophen in H-EMT were found to be mostly polaron states.
Keywords
encapsulation
cluster
host-guest reaction
hexagonal faujasite
polythiophen
Published Date
1997-01-10
Publication Title
岡山大学環境理工学部研究報告
Publication Title Alternative
Journal of the Faculty of Environmental Science and Technology, Okayama University
Volume
volume2
Issue
issue1
Publisher
岡山大学環境理工学部
Publisher Alternative
Faculty of Environmental Science and Technology, Okayama University
Start Page
137
End Page
143
ISSN
1341-9099
NCID
AN10529213
Content Type
Departmental Bulletin Paper
Related Url
http://www.okayama-u.ac.jp/user/est/homeJapan.html
language
日本語
File Version
publisher
Refereed
False
Eprints Journal Name
fest