JaLCDOI 10.18926/fest/11649
Title Alternative Morphology Control of Aromatic Polymers during Polymerization
FullText URL 001_221_227.pdf
Author Yamashita, Yuhiko| Kimura, Kunio| Tsugita, Hiroshi| Yokoyama, Fumiyoshi|
Abstract Morphology and formation mechanism of poly (4'-oxy-4-biphenylcarbonyl) (POBP) crystals obtained by solution polymerization were firstly treated. It was concluded that the formation mechanism of the bundlelike aggregates of fibrillar crystals in POBP was fundamentally simillar to that in POB whiskers. Secondly the copolymerization effects of m-acetoxybenzoic acid and 4-(4-acetoxyphenyl) benzoic acid on the morphology of POB whiskers were studied. The experimental results strongly supported our proposal for the formation mechanism of whiskers which was consisted of crystallization of oligomers with a critical length as lamellae from solution and solid state polymerizationof oligomers between lamellae. Finally, the formation mechanism of poly (p-oxycinnamoyl) spherical products during solution polymerization was treated. The formation of these spherical products could be understood by overlapped phase diagram of melting depression curve and consolute curve of oligomers-solvent system.
Keywords morphology control aromatic polymers phase separation polymer whisker polymer beads rigid rod polymers
Publication Title 岡山大学環境理工学部研究報告
Published Date 1996-03
Volume volume1
Issue issue1
Start Page 221
End Page 227
ISSN 1341-9099
language 日本語
File Version publisher
NAID 120002313893