Author 内田 哲也|
Published Date 2002-09-30
Publication Title
Content Type Thesis or Dissertation
JaLCDOI 10.18926/14136
FullText URL Mem_Fac_Eng_39_1_16.pdf
Author Uchida, Tetsuya| Ishimaru, Sanae| Shimamura, Kaoru| Uji, Akihito| Matsuo, Toshihiko| Ohtsuki, Hiroshi|
Abstract PE film was treated with fuming nitric acid at 80℃ for 20 min, resulting in introduction of COOH moieties on the film surface. The COOH’s were reacted with ethylenediamine, whose amino groups were used for linking with (2-[4-(dibutylamino)phenyl]ethenyl)-3-carboxy-methylbenzo-thiazolium, photoelectric dye (NK-5962), which absorbs visible light and converts the photon energy to electric potentials. The dye molecules were immobilized on the PE film surface and they were able to stimulate chick retinal tissues on incidence of visible light. These facts hopefully lead to development of an artificial retinal prosthesis.
Publication Title Memoirs of the Faculty of Engineering, Okayama University
Published Date 2005-01
Volume volume39
Issue issue1
Start Page 16
End Page 20
ISSN 0475-0071
language 英語
File Version publisher
NAID 120002308066
JaLCDOI 10.18926/15350
FullText URL Mem_Fac_Eng_OU_35_29.pdf
Author Shimamura, Kaoru| Munesawa Yuhji| Uchida, Tetsuya|
Abstract Poly (ethylene-block-vinyl alcohol), which consisted of both hydrophobic and hydrophilic blocks, was prepared by using polyethylene single crystals as starting material. Polyethylene single crystals reacted with fuming nitric acid resulting in long methylene chains with functional groups such as COOH and NO(2) at the ends (the chain length were almost same as the lamellar thickness of polyethylene single crystal). The functionalized methylene chains were allowed to react with 4-aminostyrene to give corresponding amides, i.e., methylene chains with vinyl groups at the ends (macromer). The macromers were extended by block-copolymerization with vinyl acetate, then saponified resulting in PE/PVA block co-polymer. The block copolymer was molded into sheets which were subsequently heat-treated in contact with hydrophilic or hydrophobic media. Depending on the media, the sheet surface changed at high temperature reversibly from hydrophilic to hydrophobic and vice versa. The surface property was fixed by quenching because both blocks were able to crystallize. Thus the surface of this material can be tailored for various purposes at high temperature, and then used in stable at room temperature.
Publication Title Memoirs of the Faculty of Engineering, Okayama University
Published Date 2001-03-27
Volume volume35
Issue issue1-2
Start Page 29
End Page 34
ISSN 0475-0071
language 英語
File Version publisher
NAID 120002307155
JaLCDOI 10.18926/15352
FullText URL Mem_Fac_Eng_OU_35_35.pdf
Author Shimamura, Kaoru| Uchida, Tetsuya| Inoue, Tomohiro|
Abstract Rigid polymer, poly(p-phenylene benzobisthiazole), formed lamellar crystals where the molecular chains were oriented perpendicular to the lamellae. It was supposed that, because of wide distribution in the chain length, the lamellar surface bristled with the chain cilia among which many voids were included. Crystallographically, this region afforded us a transitional structure from full to deficient packings of chains. The structure was analyzed using the scanning probe microscope. In the course the method for imaging one molecular chain end was developed. From the images it was concluded that an isolated long cilius did not move so violently at room temperature.
Publication Title Memoirs of the Faculty of Engineering, Okayama University
Published Date 2001-03-27
Volume volume35
Issue issue1-2
Start Page 35
End Page 40
ISSN 0475-0071
language 英語
File Version publisher
NAID 120002307784
JaLCDOI 10.18926/19622
FullText URL Mem_Fac_Eng_OU_31_1_5.pdf
Author Shimamura, Kaoru| Zhang Chunxiao| Uchida, Tetsuya|
Abstract Rigid polymer poly(p-phenylene benzobisthiazole) was crystallized from dilute solution. Electron microscopy showed that upon quenching, flat fibrils with several nm thick were produced. Subsequent heat treatment in solvent changed the fibril into "shish-kebab". On the other hand, by isothermal crystallization, an aggregate of parallel rod-like crystals was obtained. The molecular chains were accommodated normal to the rod. Based on the observation of crystal morphology, the isothermal crystallization mechanism was proposed. Because of regidity of polymer chains and wide distribution of the molecular length, the chain ends were inevitably included within the crystals resulting in crystal defects such as axial shift, lattice curvature and edge dislocation which were directly observed by lattice imaging.
Publication Title Memoirs of the Faculty of Engineering, Okayama University
Published Date 1996-12-27
Volume volume31
Issue issue1
Start Page 5
End Page 10
ISSN 0475-0071
language 英語
File Version publisher
NAID 120002309167
JaLCDOI 10.18926/19624
FullText URL Mem_Fac_Eng_OU_31_1_11.pdf
Author Zhang Chunxiao| Tanigawa Satoshi| Uchida, Tetsuya| Shimamura, Kaoru|
Abstract Poly[(benzo[1,2-d:5,4-d']bissthiazole-2,6-diyl)-1,4-phenylene](cis-PBZT)with a relatively high molecular weight was prepared by a new synthesis route. Properties of the synthesized polymer, such as thermostability, liquid crystallinity etc. were investigated and compared with those of trans-PBZT. cis-PBZT was crystallized from dilute solution and the electron microscopy showed that the precipitate was a rod-like crystal similar to that of trans form. In spite of rigid nature of the back bone, cis-PBZT showed poor crystallinity.
Publication Title Memoirs of the Faculty of Engineering, Okayama University
Published Date 1996-12-27
Volume volume31
Issue issue1
Start Page 11
End Page 17
ISSN 0475-0071
language 英語
File Version publisher
NAID 120002309203
FullText URL Heliyon_5_6_01936.pdf
Author Matsuo, Toshihiko| Uchida, Tetsuya| Yamashita, Koichiro| Takei, Shigiko| Ido, Daisuke| Fujiwara, Atsushi| Iino, Masahiko| Oguchi, Masao|
Keywords Bioengineering Neuroscience Physiology Zoology
Published Date 2019-06-30
Publication Title Heliyon
Volume volume5
Issue issue6
Publisher Elsevier Science
Start Page e01936
ISSN 24058440
Content Type Journal Article
language 英語
OAI-PMH Set 岡山大学
Copyright Holders © 2019 The Authors.
File Version publisher
PubMed ID 31294104
DOI 10.1016/j.heliyon.2019.e01936
Web of Sience KeyUT 000473818300195
Related Url isVersionOf https://doi.org/10.1016/j.heliyon.2019.e01936
Title Alternative Investigator (doctor)-initiated clinical trial of photoelectric dye-coupled thin film (Okayama University-type) retinal prosthesis
FullText URL 127_223.pdf
Author Matsuo, Toshihiko| Uchida, Tetsuya|
Keywords 人工網膜 OUReP 医師主導治験 色素結合薄膜 網膜色素変性
Publication Title 岡山医学会雑誌
Published Date 2015-12-01
Volume volume127
Issue issue3
Start Page 223
End Page 229
ISSN 0030-1558
Related Url isVersionOf https://doi.org/10.4044/joma.127.223
language 日本語
Copyright Holders Copyright (c) 2015 岡山医学会
File Version publisher
DOI 10.4044/joma.127.223
NAID 130005116816
Author Alamusi| Matsuo, Toshihiko| Hosoya, Osamu| Tsutsui, Kimiko M.| Uchida, Tetsuya|
Published Date 2013-09
Publication Title Journal of Artificial Organs
Volume volume16
Issue issue3
Content Type Journal Article
Author Kawata, Tetsuhiro| Matsuo, Toshihiko| Uchida, Tetsuya|
Published Date 2014-06-25
Publication Title SpringerPlus
Volume volume3
Content Type Journal Article